This section includes 7 InterviewSolutions, each offering curated multiple-choice questions to sharpen your Current Affairs knowledge and support exam preparation. Choose a topic below to get started.
| 1. |
If 500cm^3 of hydrogen diffused in 16 minutes through a fine hole, how much time does the same volume of ozone (O_3) take for diffusion? |
| Answer» SOLUTION :78.4 MIN | |
| 2. |
If 500 ml of 0.4 M AgNO_(3) is mixed with 50 ml of 2 M NH_(3) solution then what is the concentration of [Ag(NH_(3))]^(+) in solution (K_(t), [Ag_(NH_(3))]^(+) = 10^(3), K_(f_(2)) [Ag(NH_(3))_(2)]^(+)= 10^(4)) |
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Answer» `3.33 xx 10^(-7) M` Due to very high value of `K_(f), Ag^(+)` is mainly CONVERTED into COMPLEX. `Ag_((aq))^(+)+2NH_(3(aq))hArr[Ag(NH_(3))_(2)]_((aq))^(+)` `{:(0.2,1,),(x,0.6,02):}` `{:([Ag(NH_(3))_(2)]_((aq))^(+)hArr,[Ag(NH_(3))]_((aq))^(+),+NH_(3(aq))),(0.2-y,y,0.6+y),(0.2,,0.6):}` `(1)/(K_(f_(2))) = (y xx 0.6)/(0.2) = (1)/(10^(4))` `y = [Ag(NH_(3))]^(+) = 3.33 xx 10^(-5) M` |
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| 3. |
if 500 mL of 0.4 M AgNO_3 is mixed with 500 mL of 2M NH_3 solution the what is the concentration ofAg (NH_3 ) ^(+)in solution?[Given :K_(f_1) [Ag (NH_3) ^(+)] =10 ^(3) , K _(f_2)[Ag (NH_3)_2^(+) ]= 10^(4) ] |
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Answer» ` 3.33 xx 10^(-7)M` ` K_(f_1) xx K_(f_2)=10 ^(7) ` Due to high `K_f` value , most of the `Ag^(+) ` converted into` [Ag(NH_3)_2]^(+) ` `{:( Ag^(+) +,2NH_3 hArr, [Ag(NH_3)_2 ]^(+)), (0.2 M, 1M, 0), (, 1-04-0.6M, 0.2M):} ` ` {:([Ag(NH_3)_2]^(+) ,hArr ,Ag(NH_3)^(+), +NH_3) ,( 0.2 M, 0, 0.6M),( 0.2-y, y, 0.6+y),(~~0.2 , , ~~0.6):}` ` (1)/(10^(4) )= (yxx 0.6)/(0.2) =3y rArry =3.33 xx 10 ^(-5) M` |
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| 4. |
If 50ml of 0.2M KOH is added to 40 mlof 0.5 M HCOOH. the pH of the resulting solutions is (Ka = 1.8 xx 10^(-4) log 18= 1.26) |
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Answer» ` 3.74` ` THEREFORE" Acidic BUFFER pH " = pKa +log ""( S)/(A) ` ` = 4- log 1.8 + log"" ( 50 XX 0.2 )/(40 xx 0.5 -50 xx 0.2 ) ` ` =4-0.26 +log "" (10)/(20 - 10 )= 3.74` |
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| 5. |
If 50 kJ of energy is needed for muscular work to walk a distance of 1 km, then how much glucose one has to consume to walk a distance of 5km provided only 30% energy is available for muscular work. The enthalpy of combustion of glucose in 3000 kJ mol^(-1). |
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Answer» 75 g Energy provided by 1 mol of GLUCOSE= 3000 kJ Actual energy provide = `3000 xx (30)/(100) = 900 kJ` 900 kJ of energy require glucose = 180 g 750 kJ of energy require glucose = `(180 xx 750)/(900) = 150 g` |
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| 6. |
If 5.0 g of Al react with 4.45 g of O_(2), empirical formula of aluminium oxide is |
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Answer» `Al_(2)O_(3)` weight 5 : 4.45 MOLES = `(5)/(27):(4.45)/(16)` = 80 : 120 = 2 : 3 |
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| 7. |
If 5 ml of methane is completely burnt the volume of oxygen required and the volume of CO_(2) formed under the same conditions are |
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Answer» 5 ML , 10 ml |
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| 8. |
If 40g of CaCO_3 is treated with 40g of HCl, which of the reactants will acts as limiting reagent? |
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Answer» `CaCO_3` 100g of `CaCO_3` reacts with 73g of HCl 40g of `CaCO_3 " will reacts with " 73/100xx40=29.2g` of HCl SINCE `CaCO_3` iscompletely consumed and some AMOUNT (40-29.2=10.8g) ofHCl remains unreacted and hence, `CaCO_3` is limiting reagent. |
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| 9. |
If 4 g of NaOH dissolves in 36 g of H_(2)O, calculate the mole fraction of each component in the solution. Also, determine the molarity of solution (specific gravity of solution is 1 g mL^(-1)). |
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Answer» SOLUTION :NUMBER of moles of NaOH, `n_(NaOH)= (4)/(40) = 0.1` mol `{n=("Mass(g)")/("Molar mass")}` Similarly, `n_(H_(2)O)=(36)/(18)=2` mol Mole fraction of solute `X_(NaOH) = ("moles of NaOH")/("moles of NaOH" + "moles of "H_(2)O)` `X_(NaOH)=(0.1)/(0.1+2)=0.0476` `X_(H_(2)O)=(n_(H_(2)O))/(n_(NaOH)+n_(H_(2)O))` `=(2)/(0.1+2)=0.9524` Total mass of solution `=("mass of solute")+("mass of solvent")` `=4+36=40g` Volume of solution `=("Mass of solution")/("SPECIFIC gravity")` `=(40g)/(1g mL^(-1))=40 mL` Molarity `=("Moles of solute " xx 1000)/("Volume of solution(mL)")` `=(0.1xx1000)/(40) = 2.5M` |
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| 10. |
If 32 g of O_(2)contain 6 022 xx 10^23 molecules at NTP then 32 g of S, under same conditions, will contain, |
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Answer» `6.022 XX 10^(23)` S |
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| 11. |
If 3.1gm Phospherous is present in a sample ofCa_(3)(PO_(4))_(2) the what is the weight of oxygen in the sample? |
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Answer» Solution :Mol. WT of `Ca_(3)(PO_(4))_(2)` =310 gms. It contains 62g of phasphorus `:.` wt. of `Ca_(3)(PO_(4))_(2)` that contains 3.1 G of phosphorous `=(3.1xx310)/(62)`=15.5gm. |
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| 12. |
If 30 mL of H_(2) and 20 mL of O_(2) react to form water, what is left at the end of the experiment ? |
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Answer» 10 mL of `H_(2)` VOLUME of `O_(2)` left uncreacted `=20-15=5 mL` |
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| 13. |
If 3 litre of 1 M Ag_(2)SO_(4) is mixed with 4 litre of 1M NaCl solution, then what will be the sum of molarity of all ions? |
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Answer» 7 M |
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| 14. |
If 3-hexanone is reacted with NaBH_(4) followed by hydrolysis with D_(2)O, the product will be : |
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Answer» `CH_(3)CH_(2)CH(OD)CH_(2)CH_(2)CH_(3)` |
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| 15. |
If 25 mL of CO_(2) diffuses out of a vessel in 75 seconds, what volumeof SO_(2) would diffuse out in the same time under the same conditions ? |
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Answer» |
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| 16. |
If 240g of carbon is taken in a container to convert it completely to CO_(2) but in industry it has taken found that 280g of CO was also formed along with CO_(2). Find the percentage yeild of CO_(2). The reactions occuring are: C + O_(2) rightarrow CO_(2), C + (1/2)O_(2) rightarrow CO |
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Answer» 0.25 |
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| 17. |
If 25 ml 0.2 M Ca(OH)_2 is neutralized by 10 ml, 1 M HCl than the pH of solution is ….. |
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Answer» 1.37 `=2xxM_1xxV_1` `=2xx0.2 xx25=10` For HCl = `N_2V_2=10xx1` = 10 `THEREFORE` Mole of Acid = Moles of Base So pH = 7.0 |
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| 18. |
If 240mL of a gas X diffuses through a porous membrane in 20 min whereas the same volume of methane diffuses in 10 min at the same temperature and pressure, the molar mass in g mol^(-1) of gas X is |
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Answer» 128 |
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| 19. |
If 216g residue is obtained from 0.5 ml silver salt, |
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Answer» `N = 4` molar mass `=58 +(165) n = 718g//mol` |
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| 20. |
If 200 mL of N//10 HCl were added to 1 g calcium carbonate, what would remain after the reaction ? |
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Answer» `CaCO_(3)` |
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| 21. |
If 200 MeV energy is released in the fission of a single nucleus of ""_(92)^(235)U how many fissions must occur per second to produce a power of 1k W |
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Answer» `22222 "sec"^(-1)` `=200xx10^(6) eV=200xx10^(6)xx1.6xx10^(-19) J` `=3.2xx10^(-11) J` But ENREGY needed =1 kW `1xx10^(3) W=1xx10^(3) J s^(-1)` Number of fissions required `=("Energy required")/("Energyreleased per fission")` `=(1xx10^(3) J s^(-1))/(3.2xx10^(-11))=3.125 xx10^(13) s^(-1)` |
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| 22. |
If 20 ml of 2xx10^(-5) BaCl_(2) solution is mixed with 20 ml of 1xx10^(-5) M Na_(2)SO_(4) solution, will a ppt. form ? (K_(sp) "for" BaSO_(4) " is" 1.0xx10^(-10)) |
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Answer» |
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| 23. |
If 2-pentanone is reacted with NaBH_(4) follwed by hydrolysis with D_(2)O the product will be |
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Answer» `CH_(3)CH(OD)CH_(2)CH_(2)CH_(3)` |
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| 24. |
If 2 moles of solute is dissolved in 500 g solvent then the molality of solution is .......... |
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Answer» 2.5 |
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| 25. |
If 2 litres of butane is completely burnt the volume of CO_(2) obtained under the same conditions would be |
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Answer» 2 lit |
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| 26. |
If 1m solution of benzoic acid in benzene has a freezing point depression of 3.84 ^(@)C . (K_(f)=5.12^(@)C mol^(-1)kg) and boiling point elevation of 2.53^(@)C(K_(b) =2.53^(@)C "mol"^(-1) kg), then select the correct statement/s :lt brgtstatement I : there aredimar formation when under =going freezing Statement II : there are no change when undergoing boiling Statement III : reverse of I and II ltbr. Statement IV : dimer formation in freezing and boiling state |
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Answer» I, II |
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| 27. |
If 1.50g of H_(2)C_(2)O_(4).2H_(2)O were heated to drive of the water of hydration, how much anhydrous H_(2)C_(2)O_(4) would remain? |
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Answer» 0.34g |
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| 28. |
If 150cc of CO effused in 25 seconds, what volume of methane would effuse in the same time? |
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Answer» |
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| 29. |
If 150 kJ of energy is needed for muscular work to walk a distance of one km , then how muchof glucoseone has to consumeto walk a distanceoffive km, provided only 30% energy is available for muscular work. Theenthalpy of combustion of glucoseis 3000kJ mol^(-1) |
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Answer» 75g 1 mole of glucose , `C_(6)H_(12)O_(6) ( 180g)` gives THEORETICALLY energy `= 3000kJ` Actual energy available`= ( 30)/( 100) XX 3000 = 900 kJ` Thus, for 900kJ of energy , glucose required `= 180 g` `:. `For 750 kJ of energy , glucose required`= ( 180)/( 900) xx750 g = 150 g` |
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| 30. |
If 1.5 moles of oxygen combine with Al to form Al_(2)O_(3). The mass of Al in grams. (Atomic mass of Al = 27) used in the reaction is : |
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Answer» 2.7 Mass of Al in grams USED `=2xx27=54` G |
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| 31. |
If 1.27 g Cu is obtained by reduction of one sample of Cu_(2)O then the amount of oxygen in sample is .......... g. |
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Answer» 16 Mass of O in sample `=16 g` If `Cu 127 g = O` is 16 g `:.` If Cu `1.27g=(?)` `:.(16xx1.27)/(127) = 0.16g` oxygen |
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| 32. |
If 1.26 g of oxalic acid is dissolved in 250 mL of solution, find its normality. The equivalent mass of oxalic acid is 63. |
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Answer» |
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| 33. |
If 11.1 mg of CaCl_(2) and 12 mg of MgSO_(4) are present in 2 L of water, what is its hardness (in gram CaCO_(3)/ppm)? |
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Answer» 5 `=111 times 10^(3)mg=100 times 10^(3)mg` `underset(underset(=120 times 10^(3)mg)(24+32+64))(MgSO_(4)) equiv underset(underset(=100 times 10^(3)mg)(40+12+40))(CaCO_(3))` `111 times 10^(3)" mg of "CaCl_(2)=100 times 10^(3)" mg of "CaCO_(3)` `11.1" mg of "CaCl_(2)=(100 times 10^(3) times 11.1)/(111 times 10^(3))mg` of ` CaCO_(3)=` 10 of `CaCO_(3)` SIMILARLY, `120 times 10^(3)" mg of "MgSO_(4)` `=100 times 10^(3)" mg of "CaCO_(3)` 12 mg of `MgSO_(4)=(100 times 10^(3))/(120 times 10^(3)) times 12" mg of "CaCO_(3)` `""=10" mg of "CaCO_(3)` In 2 L of water, total weight of `CaCO_(3)` `=10+10=20` mg In 1 L of water, total weight of `CaCO_(3)` `20/2mg=10mg` In `10^(6)` mg of water, total weight of `CaCO_(3)=10` mg So, in `10^(6)` part water, hardness of water in terms of `CaCO_(3)=10` ppm |
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| 34. |
If 11.1 mg of CaCl_2 and 12mg of MgSO_4are present in 2 litres of water, what is its hardness (in grams of CaCO_3/ppm)? |
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Answer» 5 |
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| 35. |
If 10^(21) molecules are removed from 200 mg of CO_(2), the number of moles of CO_(2) left is |
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Answer» `2.88xx10^(-3)` |
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| 36. |
If 100mL of 1M HCl is added to 150mL of 1M NaOH, What is the final nature and concentration of resultant solution. |
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Answer» Solution :NUMBER of MILLIMOLES of acid `=100xx1=100` Number of millimoles of base `=150xx1=150` Base is in excess. Hence resultant solution is basic and concentration`=(150-100)/(250)=(50)/(250)=0.2M` |
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| 37. |
If 100 mL of the acid is neutralised by 100 mL of 4 M NaOH, the purity of concentrated HCl (sp. Gravity =1.2) is : |
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Answer» 0.12 |
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| 38. |
If 100 ml hydrogen chloride is completely decomposed the volume of H_(2) formed will be (P and T are constant). |
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Answer» 20ml |
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| 39. |
If 100 mt. of acid 2NH_(2)O_(2) is allowed to react with KMnO_(4) solution till there is a light tinge of purple colour. The volume of oxygen produced at STP is |
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Answer» 2.24L 100 ML of 2N (i.e., 11.2 Vol) of `H_2O_2` produce 1.12 LT of Oxygen |
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| 40. |
If ten volumes of dihydrogen gases react with five volumes of dioxygen gases that, how many volumes of water vapour would be produced ? |
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Answer» Solution :`underset(2 volumes)(2H_(2(G))) + underset(1 volume)(O_(2(g))) rarr underset(2 volumes)(2H_(2)O)` Thus 2 volumes of `H_(2)`REACTS with 1 volume of `O_(2)` to produce 2 volumes of `H_(2)O_((g))`. `:.` 10 volumes of `H_(2)`WOULD react with 5 volumes of `O_(2)` to produce 10 volumes of `H_(2)O_((g))` , Thus 10 volumes of `H_(2)O` will be produced. |
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| 41. |
If 10 gm of a gas at atmospheric pressure is cooled from 273°C to 0°C keeping the volume constant, its pressure would become |
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Answer» 2 ATM |
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| 42. |
If 10^(-4) dm^(3) of water is introduced into a 1.0 dm^(3) flask at 300 K, how many moles of water are in the vapour phase when equilibrium is established ? (Given : Vapour pressure of H_(2)O at 300 K is 3170 Pa , R=8.314 JK^(-1)mol^(-1)) |
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Answer» `4.46xx10^(-2)mol` Also, `V=1 dm^(3)=10^(-3), T=300" K"` PV=nRT, `N=(PV)/(RT)=(3170xx10^(-3))/(8.314xx300)` `=1.27xx10^(-3)` |
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| 43. |
If 10^(-4) dm^(3) of water is introduced into a 1.0 dm^(3). Flask at 300 K, calculate the number of moles of water is in vapour phase when equililbrium is established ? (V.P. of H_(2)O at 300 K is 3170 Pa ) |
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Answer» Solution :`P_(H_(2)O) = 3170 Pa = 3.17 xx 10^(-2)` atm From the ideal gas equation, PV = NRT NUMBER of moles, `n = (PV)/(RT)` ` = (3.17 xx 10^(-2) xx 1)/(0.0821 xx 300) = 1.27 xx 10^(-3)` mol |
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| 44. |
If 1 mole of CH_(3)COOH and 1 mole of C_(2)H_(5)OH are taken in 1 litre flask, 50% of CH_(3)COOH is converted into ester as, CH_(3)COOH_((l))+C_(2)H_(5)OH_((l))hArrCH_(3)COOC_(2)H_(5)(l)+H_(2)O_((l)) There is 33% conversion of CH_(3)COOH into ester, if CH_(3)COOH "and" C_(2)H_(5)OH have been taken initially in molar ratio x:1, find x. |
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Answer» `1-0.5 1-0.5 0.5 0.5` So, `K_(C)=(0.5xx0.5)/(0.5xx0.5)=1` Now let a moles of `CH_(3)COOH "and" b "moles of" C_(2)H_(5)OH` are TAKEN: `a-(a)/(3) b-(a)/(3) (a)/(3) (a)/(3)` So, `K_(c)=((a//3)XX(a//3))/(2a//3xx(b-(a)/(3))) or 2(b-(a)/(3))=(a)/(3)` or `2b=a` or `(a)/(b)=(2)/(1)` |
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| 45. |
If 1 mole H_(2) is reacted with 1 mole of the following compound. Which double bond will be hydrogenated ? |
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Answer» c |
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| 46. |
If 1 mL of water contains 20 drops, what is the number of water molecules in the one drop of water? (A = Avogadro's number) |
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Answer» `(0.5)/(18)`A `therefore` 1 drop contians = (A)/(20 xx 18)` molecules = `(0.05A)/(18)` molecules |
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| 47. |
If 1 gram of each of the following gases are taken at STP, which of the gases will occupy (a) greatest volume and (b) smallest volume ? CO,H_(2)O,CH_(4),NO |
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Answer» Solution :MOLAR VOLUME ofa gas, i.e., volume of 1 mole of the gas =22.7 L at STP 1 mole of CO=28 g, i.e., 28 g of CO have volume =22.7 L at STP `:.` 1 g of CO will have volume `=(22.7)/(28)` L at STP Similarly, `""1 g of H_(2)O" vapour"=(22.7)/(18)`L,1 g `CH_(4)=(22.7)/(16)"L",1 g NO=(22.7)/(30)"L"` Thus, 1 g of `CH_(4)` will occupy MAXIMUM volume and 1 g of NO will occupy minimum volume at STP. |
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| 48. |
If 1 kg of water contains 12 mg magnesium sulphate its degree of hardness is |
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Answer» 50 ppm `MgSO_(4)` HARDNESS `=(12xx10^(-3)g)/(10^(3)g)xx10^(6)g=12` ppm `rArr 12g of MgSO_(4)` in `10^(6)g` of water hardness in terms of `CaCO_(3)=12xx(100)/(12)=10` ppm |
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| 49. |
If 1 kg of water contains 12 mg of magnesium sulphate its degree of hardness is |
| Answer» Answer :D | |
| 50. |
If 1 g of each of the following gases are taken at STP, which of the gases will occupy (a) greatest volume and (b) smallest volume ?CO, H_(2)O, CH_(4), NO |
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Answer» SOLUTION :From Avogardro.s law, we know that Bolume of 1 mole of GAS = gram molecular mass = 22.4 L at STP. Volume of occupied by 28 g CO (1 MOL CO) = 22.4 L at STP. (`because` Molar mass of `CO=12+16=28 g mol^(-1)`) `terefore` Volume occupied by 1 g `CO=(22.4)/(28)` L at STP. Similarly, Volume occupied by 1 g `H_(2)O=(22.4)/(18)` L at STP.(`because` Molar mass of `H_(2)O = (2xx1)+16)=18 g mol^(-1)`) Volume occupied by 1 g `CH_(4)=(22.4)/(16)` L at STP.(`because` Molar mass of `CH_(4)=12+(4xx1)=16 g mol^(-1)`) Volume occupied by 1 g NO `= (22.4)/(30)` L at STP.(`because` Molar mass of NO `= 14+16 = 30 g mol^(-1)`) Hence, 1 g `CH_(4)` will occupy maximum volume and 1 g of NO will occupy minimum volume at STP. |
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